Influence of flame retardants on the melt dripping behaviour of thermoplastic polymers

Matzen, Melissa, Kandola, Baljinder K. ORCID: 0000-0002-3621-3724, Huth, Christian and Schartel, Bernhard (2015) Influence of flame retardants on the melt dripping behaviour of thermoplastic polymers. Materials, 8 (9). pp. 5621-5646. ISSN 1996-1944

[img]
Preview
Text
114-Matzen_Kandola_Huth_Schartel_ Materials 2015_Open access.pdf - Published Version
Available under License Creative Commons Attribution.

Download (4MB) | Preview
Official URL: http://www.mdpi.com/journal/materials

Abstract

Melt flow and dripping of the pyrolysing polymer melt can be both a benefit and a detriment during a fire. In several small-scale fire tests addressing the ignition of a defined specimen with a small ignition source, well-adjusted melt flow and dripping are usually beneficial to pass the test. The presence of flame retardants often changes the melt viscosity crucially. The influence of certain flame retardants on the dripping behaviour of four commercial polymers, poly(butylene terephthalate) (PBT), polypropylene (PP), polypropylene modified with ethylene-propylene rubber (PP-EP) and polyamide 6 (PA 6), is analysed based on an experimental monitoring of the mass loss due to melt dripping, drop size and drop temperature as a function of the furnace temperature applied to a rod-shaped specimen. Investigating the thermal transition (DSC), thermal and thermo-oxidative decomposition, as well as the viscosity of the polymer and collected drops completes the investigation. Different mechanisms of the flame retardants are associated with their influence on the dripping behaviour in the UL 94 test. Reduction in decomposition temperature and changed viscosity play a major role. A flow limit in flame-retarded PBT, enhanced decomposition of flame-retarded PP and PP-EP and the promotion of dripping in PA 6 are the salient features discussed.

Item Type: Article
Additional Information: This article belongs to the Special Issue Influence of Thermo-Physical and Thermo-Optical Properties on the Fire Behavior of Polymers
Uncontrolled Keywords: fire retardant, viscosity, melt dripping, reaction-to-small-flame, UL 94
Divisions: School of Engineering > Engineering
University of Bolton Research Centres > Institute for Materials Research and Innovation
Depositing User: Tracey Gill
Date Deposited: 21 Mar 2018 11:43
Last Modified: 21 Mar 2018 11:43
Identification Number: 10.3390/ma8095267
URI: http://ubir.bolton.ac.uk/id/eprint/1472

Actions (login required)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics

>